As a teacher, your students' usernames are always visible in the Classrooms area of the teacher's dashboard.
Open the Classrooms area from the main menu on the Discovery Education homepage.
Select the appropriate classroom tile and click on the ellipsis/triple dot icon on the right-hand side. Choose Manage this class.
You will then be shown a screen where all the details about your class can be seen. Choose the Pupils tab.
All the students within your class will be listed with their Username in the second column.
Due to GDPR guidelines, passwords are not normally visible in the programme, but after generating passwords for your students for the first time, you will be given an option to save or print a document listing all the student passwords. This is the only opportunity that you will have to save or print this document.
If a student forgets their password and you do not have access to this document, you will need to reset their password. Please read this article for instructions on how to do this.